Aufsatz
The electronic structure of the group 6 oxyanions [MO_4]^2-, where M = Cr, Mo, W, and element 106
Zusammenfassung
The electronic structure of the group 6 oxyanions [MO_4]^2-, where M = Cr, Mo, W, and element 106 have been calculated using the Dirac-Slater Discrete Variational method. Results of the calculations show a relative decrease in the metal-oxygen bond strengths for the [E106O_4]^2- ion in the solid state compared to that for the [WO_4]^2- anion. Calculated energies of the electronic charge-transfer transitions are indicative of a strong possible luminescence of [El06O_4]^2- in the blue-violet area. In solutions [El06O_4]^2- will be the most stable ion out of the entire series. Estimated reduction potential E^0 (El06O^2-_4/E106O^3-_4) equal to -1.60V shows only a slightly increased stability of the +6 oxidation state for element 106 in comparison with W.
Zitierform
In: Radiochimica acta. - Muenchen : Oldenbourg, 65.1994, S. 13-17Zitieren
@article{urn:nbn:de:hebis:34-2008102024591,
author={Pershina, Valerija G. and Fricke, Burkhard},
title={The electronic structure of the group 6 oxyanions [MO_4]^2-, where M = Cr, Mo, W, and element 106},
year={1994}
}
0500 Oax 0501 Text $btxt$2rdacontent 0502 Computermedien $bc$2rdacarrier 1100 1994$n1994 1500 1/eng 2050 ##0##urn:nbn:de:hebis:34-2008102024591 3000 Pershina, Valerija G. 3010 Fricke, Burkhard 4000 The electronic structure of the group 6 oxyanions [MO_4]^2-, where M = Cr, Mo, W, and element 106 / Pershina, Valerija G. 4030 4060 Online-Ressource 4085 ##0##=u http://nbn-resolving.de/urn:nbn:de:hebis:34-2008102024591=x R 4204 \$dAufsatz 4170 7136 ##0##urn:nbn:de:hebis:34-2008102024591
2008-10-20T09:47:54Z 2008-10-20T09:47:54Z 1994 0033-8230 urn:nbn:de:hebis:34-2008102024591 http://hdl.handle.net/123456789/2008102024591 482299 bytes application/pdf eng Urheberrechtlich geschützt https://rightsstatements.org/page/InC/1.0/ 530 The electronic structure of the group 6 oxyanions [MO_4]^2-, where M = Cr, Mo, W, and element 106 Aufsatz The electronic structure of the group 6 oxyanions [MO_4]^2-, where M = Cr, Mo, W, and element 106 have been calculated using the Dirac-Slater Discrete Variational method. Results of the calculations show a relative decrease in the metal-oxygen bond strengths for the [E106O_4]^2- ion in the solid state compared to that for the [WO_4]^2- anion. Calculated energies of the electronic charge-transfer transitions are indicative of a strong possible luminescence of [El06O_4]^2- in the blue-violet area. In solutions [El06O_4]^2- will be the most stable ion out of the entire series. Estimated reduction potential E^0 (El06O^2-_4/E106O^3-_4) equal to -1.60V shows only a slightly increased stability of the +6 oxidation state for element 106 in comparison with W. open access In: Radiochimica acta. - Muenchen : Oldenbourg, 65.1994, S. 13-17 Pershina, Valerija G. Fricke, Burkhard
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